English: We study the nature of the scalar D∗0 meson from the viewpoint of chiral symmetry. With the linear representation of chiral symmetry, we construct the Dπ scattering amplitude satisfying the chiral low-energy theorem, in which the D∗0 meson appears as an s-wave resonance. We show that the properties of the D∗0 meson can be successfully reproduced as the chiral partner of the D meson coupled with the Dπ scattering states. At the same time, we find that the spectral function and the pole position of D∗0 are not very sensitive to the reduction of the chiral condensate, indicating the importance of the dressing of the bare state by the Dπ molecular component.