Nuklear
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- Image:Piclamilast synthesis.png was uncategorized on 15 June 2010 CategorizationBot (talk) 10:51, 16 June 2010 (UTC)
Epibatidine edit
Hi Nuklear. I just wanted to let you know that I have reverted your change to File:Epibatidine structure.png. I like your image fine, but the file I uploaded is intended to conform to w:en:Wikipedia:Manual of Style (chemistry)/Structure drawing. Please feel free to upload your version as a separate file. Thanks. Edgar181 (talk) 14:40, 5 August 2009 (UTC)
Hi Nuklear. I've reverted your change to File:Pictet-Spengler Reaction Mechanism.png. Please do not upload your file over existing files. Please upload your version as a separate file. Thank you. --Choij (talk) 04:30, 12 October 2009 (UTC)
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Cwbm (commons) (talk) 13:39, 18 July 2011 (UTC)
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Structural formulae edit
Dear Nuklear,
may you draw your formulae more according to the Manual of Style?--Kopiersperre (talk) 19:16, 4 July 2014 (UTC)
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DMacks (talk) 16:06, 13 July 2014 (UTC)
Abacavir edit
Nuklear your synthesis is incorrect, you make the wrong stereoisomer in the final product. In essence you make the 1,2-product, not the 1,4-product. look at the strucures!! ok thanks, i edit to correct mistake. sorry i did that, my mistake. although, dan drew wrong isomer in his book 6 which probably distracted my attention.
File tagging File:Nuklear logo.jpg edit
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Motopark (talk) 10:49, 15 October 2014 (UTC)
I just copied it from google image search engine. I didn't realize that special permission was required to copy an image.
Only text only logos are allowed in Commons without OTRS-permission Motopark (talk) 10:49, 15 October 2014 (UTC)
Ropinirole edit
Your synthesis diagram for ropinirole is incorrect as it depicts synthesis of the N-isopropyl analogue not the N,N-di-n-propyl like it should be. Meodipt (talk) 02:22, 9 November 2014 (UTC)
I know but wit h the secondary amine was how Dan drew it in his book 6 page 132. Could not access journal article no password and cost $35 to view it--Nuklear (talk) 20:28, 10 November 2014 (UTC)
Vector graphics please edit
Dear Nuklear,
you've uploaded a huge amount of drug syntheses. I want to give thanks to you but it's futile and a waste of your effort, when you don't upload them as SVG (see Commons:Transition to SVG). Does your structural drawing program allow the output of SVGs?--Kopiersperre (talk) 17:46, 11 December 2014 (UTC)
Ok, here is one I uploaded for you in .svg then:
I hope that you like seeing this in .svg rather than .png format, per your request sir.--Nuklear (talk) 20:45, 11 December 2014 (UTC)
- Thanks for the prompt change. Why is there a lonely hydrogen in the left bottom of the graphics?--Kopiersperre (talk) 23:16, 11 December 2014 (UTC)
Dear Nuklear,
may you draw the synthesis of the amebicide diloxanide furoate?--Kopiersperre (talk) 00:18, 4 January 2015 (UTC)
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Error in Nitroglycerine synthesis figure edit
Your figure File:Nitroglycerine synthesis.png Shows the molecules containing four carbons. There are only three carbons in these structures. Remove the left most carbon and attach the hydroxyl to the middle carbon - similarly attach the nitroxy group to the product - 1,2,3-Trinitroxypropane (3-carbons).
Wikipedia 'List of cocaine analogues' article images needed edit
Hello,
I notice you make a lot of molecular structure 2D images. I am currently restricted to a library computer and cannot make images for upload.
I was wondering if you could assist me in my endeavor of adding certain images for inclusion at the Wikipedia 'List of cocaine analogues' page.
What I need is mostly those from Singh's SAR of Cocaine paper (45 pages in on the page finder; pg. 970 or so as enumerated on the paper itself: the chemical structures 183a-(through)-d, 184a & b, 185a-d, 186-188 on 'Scheme 42', on pg. 50 (974) structures 196a-o, 197a-g, 198a-e, 199a & b, 200 & 201a-e ... and more down to page 61 or so; namely N-modified analogs & such.)
Any help making these would be greatly appreciated. Nagelfar (talk) 21:52, 24 February 2015 (UTC)
Sure, just give me a few days & i'll look into it and try and help you with it.--Nuklear (talk) 11:09, 2 March 2015 (UTC)
- Thanks for the much needed "R=..." images... Hey, I had a question maybe you know the answer to: Is the IUPAC on given on 2'-Acetoxycocaine wrong? It is:
- (1R,2R,3S,5S)-Methyl 3-((2-acetoxybenzoyl)oxy)-8-methyl-8-azabicyclo[3.2.1]octane-2-carboxylate
- Though using the IUPAC of cocaine as a starting point my assumption would be it is supposed to be:
- methyl(1R,2R,3S,5S)-3-(2-acetoxybenzoyloxy)-8-methyl-8-azabicyclo[3.2.1]octane-2-carboxylate
- Is the stereoisomerism of this analog different in this case, and if so, would it be in other cases? If not, what is the nature of the orientation of this error and how does it related to the isomers? Nagelfar (talk) 21:03, 3 March 2015 (UTC)
Ok, I ran both names through CD and I get exactly the same structure in both cases.
So, both names are recognized by CD "convert name to structure" function.--Nuklear (talk) 03:53, 4 March 2015 (UTC)
- The structures through www.chemicalize.org are different in that one has two shaded wedge bonds (between the 2beta position & half the nitrogen bridge) and the other they are solid wedge bonds, not shaded. I thought this had to do with isomerism.
- Anyhow, I will continue to revert any "ban reverts" they put on you in the 'list of cocaine analogues' article. There is discussion on my Wikipedia user talk page to the effect that such will be tolerated but that they are considered "my edits" apparently. The images [1] & [2] need to be upgraded, the nitrogen is off and half the bridge is missing, but otherwise thank you! (For aesthetic consistency through the article I'd like the OBz abbreviation to be the fully drawn out benzoyloxy, though, but that's just personal taste.) Nagelfar (talk) 18:45, 4 March 2015 (UTC)
- I changed my mind, I like the OBz abbr. in the boxes ;-) I still need your help with those "R" & "X" images. Nagelfar (talk) 00:54, 10 March 2015 (UTC)
Thanks alot for your input to try and get done this free work. I'll look into it and try and help you as far as possible.--Nuklear (talk) 04:18, 10 March 2015 (UTC)
Misplaced N groups edit
Dear Nuklear, in many of your schemes there is a ChemDraw bug, which misplaces things stacked over a Nitrogen (NMe or NH). (For example see old version of File:Theophylline synthesis 1.svg) Could you please fix this with Inkscape before you upload?--Kopiersperre (talk) 07:39, 5 March 2015 (UTC)
Thanks for your advice. I wrote to PerkinElmer already to tell them about the problem but had no idea how to fix it.--Nuklear (talk) 09:05, 5 March 2015 (UTC)
Your account will be renamed edit
Hello,
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Unfortunately, your account clashes with another account also called Nuklear. To make sure that both of you can use all Wikimedia projects in future, we have reserved the name Nuklear~commonswiki that only you will have. If you like it, you don't have to do anything. If you do not like it, you can pick out a different name.
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22:11, 17 March 2015 (UTC)
Nuklear; your 'List of phenyltropanes' page: edit
I'm going to get to all of S. Singh's tables from here and include them but I need some of your input. Should I just title them like in that paper (i.e. 3β-(4′-Substituted Phenyl)tropanes (as sub-cat. of Phenyl ring substituted phenyltropanes) … etc.) or should I go through the classification system you have in place. (i.e. 2-Carboxymethyl esters … β,α Stereochemistry … Tricyclic Tropanes … & et cetera) if it's the latter I'm going to need your help, and if its the former how should I interpolate the tables to be incorporated between your system in place? Or should we work together and just overhaul the whole schema of the article as it now stands for something that can easily incorporate the fifty some pages Singh dedicated to phenyltropanes in that paper along with the RTI research you've already transcluded? Please get back to me, I can also do edits for you if they're constructive and you're otherwise hindered by edit-restrictions due to past policy faux pas. Nagelfar (talk) 20:16, 25 March 2015 (UTC)
Ok, he got things like meta-substituted I didn't bother about, just add those in if you want to I don't mind either way.--Nuklear (talk) 07:16, 27 March 2015 (UTC)
- What do you mean by meta-substituted? Which ones are those in the paper? (Give me a page number and I'll get them done, or some other way to decipher what you mean by meta-, if you mean substitutions of substitutions I need your input, you're more astute than I, give me the compound numbers (e.g. n-(through)-n) and I'll incorporate their tables). I still need those R-substitution/modification images in my tables at my cocaine analogues list, too. BTW Nagelfar (talk) 23:45, 27 March 2015 (UTC)
There's a few meta compounds on 933 but only dat is recorded. i included them. if u want to include anymore then be obliged, but i can't be bothered with it anymore it's getting boring now.--Nuklear (talk) 08:09, 28 March 2015 (UTC)
- OK, I understand. I'll get to the 16 & 17s, and any other I see with both an X & Y. If your interest is ever piqued again, throw me a line at which ones need to be included (did you get to the metal chelated ones?) which numbers from Singh's paper, and I'll do it for you. (On page 961 (37th) scheme 32 has ones that have a W, X, Y & Z 6/7 substitution!) Nagelfar (talk) 18:00, 28 March 2015 (UTC)
Copyright status: File:Nuklear Power.jpg edit
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Yours sincerely, JuTa 18:21, 31 March 2015 (UTC)
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The quality of the chemical structure File:31,345 structure.svg is disputed edit
Dispute notification | The chemical structure File:31,345 structure.svg you uploaded has been tagged as and is now listed in Category:Low quality chemical diagrams. Files in this category might be deleted after one month if there is no upload of an improved version, if there is no objection from the uploader or other users and if a better version exists. Please discuss on the file talk page if you feel that the dispute is inappropriate. If you agree with the dispute, you can either upload an improved version or simply allow the file to be deleted.
In all cases, please do not take the dispute personally. It is never intended as such. Thank you! --Leyo 23:18, 7 May 2015 (UTC) |
That's really picky saying Me could be confused with metal, to an organic chemist would know straight away what it means. — Preceding unsigned comment added by Nuklear (talk • contribs)
- Not every reader of Wikipedia is an organic chemist. See also en:MOS:Structure drawing#General. --Leyo 08:14, 8 May 2015 (UTC)
The factual accuracy of the chemical structure File:Bodroux-Chichibabin hexanal.svg is disputed edit
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Inquiries edit
Baclofen edit
Dear Nuklear,
may you please redraw File:Baclofen synthesis.png and File:Baclofen synthesis 2.png as SVG?--Kopiersperre (talk) 11:31, 16 June 2015 (UTC)
Ezetimibe edit
May you please draw a synthesis?--Kopiersperre (talk) 16:30, 16 September 2015 (UTC)
Swastika formulas edit
- Hi.
I was slightly shocked finding that Formula in the enwiki article. Are you aware that the swastika is a worldwide known symbol of one of the most cruel criminal political movement in history, and in some countries that sign is also illegal? So, i intervened in enwiki. May i ask if you made more drawings similar to that? --Itu (talk) 07:45, 11 November 2015 (UTC)
Yes there was one other instance of chemical formulae that could be drawn in a swastika like design. If you take meprobamate which is derived from methyl propyl malonic ester and then to do the diethyl analog. That was the only other example I have come across. This is scientific chemical formulae though rather than artistic drawings.--Nuklear (talk) 17:06, 14 November 2015 (UTC)
I found another swastika formula in the book I was studying today called Petrichloral.--Nuklear (talk) 11:50, 22 May 2016 (UTC)
Also for Loprodiol.
Your list of PTs edit
I've been doin' some work on it. Tell me what you think. (and let me know if you'd like to add any notes that I can include/adopt as my own for you) Best regards, Nuke. Nagelfar (talk) 17:19, 5 January 2016 (UTC)
- Check it out now, Nuklear. ;-j Nagelfar (talk) 22:17, 26 January 2016 (UTC)
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Hi Nuklear, from which patent did you take the scheme? It seems that from https://www.google.com/patents/US3700681 but I cannot see there the alkylation step with t-BuBr. In other Pfizer's patents t-BuNH2 is used to react with an oxirane system. Regards, Michał Sobkowski (talk) 07:34, 11 March 2016 (UTC)
Okay thanks I still need to look into this perhaps, I copied it from Lednicer book2 what was written.
https://en.wikipedia.org/w/index.php?title=Pirbuterol&oldid=666191118
You checked all the patents? because I didn't have time to look into all of it.--Nuklear (talk) 10:45, 15 March 2016 (UTC)
One double bond has 'crossed lines'. Please fix!--Kopiersperre (talk) 20:28, 16 March 2016 (UTC)
- IUPAC says (page 1961): “A crossed double bond has sometimes been used to indicate unspecified double bond configuration or a mixture of configurations. This type of bond is not considered acceptable for general use, although it may still be required by some computer software.”
- In addition, “Me” and “Et” should not be used. --Leyo 23:43, 16 March 2016 (UTC)
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Please correct your mistake or return the old image. WBR, BattlePeasant (talk) 04:19, 12 January 2017 (UTC)
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Your "boring to you" List of phenyltropanes edit
Hey Nuklear, me and user:Edgar181 have done quite a bit of work filling out your List of phenyltropanes WP page, check it out, see if it piques your interest on adding whatever remaining RTI structures we couldn't find. For instance, we couldn't find RTI-262: don't know where your main source was from, but the few omissions and corrections yet to do would be appreciated, you may be bored of it, but for some reason it still holds my interest, hoping all the effort in the interim piques a bit of follow-up interest with the pages original author, at least; At least check out it's current/latest permutation. Nagelfar (talk) 19:48, 10 May 2017 (UTC)
- (In response to yours, on my talk) Good to hear back from you finally, as well, Nuklear: I presume what you mentioned to me is a chemistry-oriented (and not just information) database? Grey-market pharmaceutical synth, how-to's etc.? (I've been thinking of adding Singh's PT synth. schematics to wiki-How-To with inter-wiki links, as a matter of fact, from here on the WP pages. I don't know if you're familiar with bluelight.org, specifically Neuroscience and Pharmacology discussion; there are very connected, intelligent, people there. Pen & paper penpals with established chemists (I know a friend in England, Sean, who writes back and forth with a well known retired chemist; said he could pull some strings ands get my U.S. felonies expunged for a visa for greymarket enterprising; this was years ago the offer came up in conversation) Nagelfar (talk) 19:34, 20 October 2017 (UTC)
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Unblock edit
{{unblock|reason=I haven't been able to contribute to this site for a number of years now over 10 years.}} — Preceding unsigned comment added by 88.105.212.47 (talk • contribs) 16:10, 19 February 2019 (UTC)
- Innuendo by the IP. Nuklear is/was not blocked here, and is a Commons user during recent years. Incnis Mrsi (talk) 17:30, 19 February 2019 (UTC)
The quality of the chemical structure File:Lu-AA42202.svg is disputed edit
Dispute notification | The chemical structure File:Lu-AA42202.svg you uploaded has been tagged as and is now listed in Category:Low quality chemical diagrams. Files in this category might be deleted after one month if there is no upload of an improved version, if there is no objection from the uploader or other users, and if a better version exists. Please discuss on the file talk page if you feel that the dispute is inappropriate. If you agree with the dispute, you can either upload an improved version or simply allow the file to be deleted.
In all cases, please do not take the dispute personally. It is never intended as such. Thank you! --Chem Sim 2001 (disc) 21:22, 12 March 2020 (UTC) |
File:Homopipramol2.svg has been listed at Commons:Deletion requests so that the community can discuss whether it should be kept or not. We would appreciate it if you could go to voice your opinion about this at its entry.
If you created this file, please note that the fact that it has been proposed for deletion does not necessarily mean that we do not value your kind contribution. It simply means that one person believes that there is some specific problem with it, such as a copyright issue. Please see Commons:But it's my own work! for a guide on how to address these issues. |
File:PAL-542.svg has been listed at Commons:Deletion requests so that the community can discuss whether it should be kept or not. We would appreciate it if you could go to voice your opinion about this at its entry.
If you created this file, please note that the fact that it has been proposed for deletion does not necessarily mean that we do not value your kind contribution. It simply means that one person believes that there is some specific problem with it, such as a copyright issue. Please see Commons:But it's my own work! for a guide on how to address these issues. |
File:Amitriptyline triangle.svg has been listed at Commons:Deletion requests so that the community can discuss whether it should be kept or not. We would appreciate it if you could go to voice your opinion about this at its entry.
If you created this file, please note that the fact that it has been proposed for deletion does not necessarily mean that we do not value your kind contribution. It simply means that one person believes that there is some specific problem with it, such as a copyright issue. Please see Commons:But it's my own work! for a guide on how to address these issues. |
— Jeff G. ツ please ping or talk to me 08:32, 9 February 2021 (UTC)
File:JNJ-Efavirenz conjunctive.png has been listed at Commons:Deletion requests so that the community can discuss whether it should be kept or not. We would appreciate it if you could go to voice your opinion about this at its entry.
If you created this file, please note that the fact that it has been proposed for deletion does not necessarily mean that we do not value your kind contribution. It simply means that one person believes that there is some specific problem with it, such as a copyright issue. Please see Commons:But it's my own work! for a guide on how to address these issues. |
— Jeff G. ツ please ping or talk to me 08:36, 9 February 2021 (UTC)
File:Parkinson.svg has been listed at Commons:Deletion requests so that the community can discuss whether it should be kept or not. We would appreciate it if you could go to voice your opinion about this at its entry.
If you created this file, please note that the fact that it has been proposed for deletion does not necessarily mean that we do not value your kind contribution. It simply means that one person believes that there is some specific problem with it, such as a copyright issue. Please see Commons:But it's my own work! for a guide on how to address these issues. |
— Jeff G. ツ please ping or talk to me 08:40, 9 February 2021 (UTC)
Hi Nuklear. What is the right title for File:Xfiles.png? Please use {{Rename}} for that, rather than {{Delete}}. Also, I noticed that you've made multiple malformed deletion requests. When you want to delete a file with the {{Delete}} template, you must follow the instructions in the template, including the "Click here to show further instructions" portion. Alternatively, you can click the "Nominate for deletion" link in the left sidebar, under the "tools" section, which does all of the work for you. Please do one of these, otherwise you create a lot of work for other people. If you don't see the "Nominate for deletion" link in the left sidebar, you can use the JavaScript method of enabling AjaxQuickDelete on Special:Preferences#mw-prefsection-gadgets once and then refresh once. — Jeff G. ツ please ping or talk to me 08:44, 9 February 2021 (UTC)
Notification about possible deletion edit
Some contents have been listed at Commons:Deletion requests so that the community can discuss whether they should be kept or not. We would appreciate it if you could go to voice your opinion about this at their entry.
If you created these pages, please note that the fact that they have been proposed for deletion does not necessarily mean that we do not value your kind contribution. It simply means that one person believes that there is some specific problem with them, such as a copyright issue. Please see Commons:But it's my own work! for a guide on how to address these issues. |
Affected:
And also:
Regards, Marbletan (talk) 16:04, 14 February 2022 (UTC)
File:Anagestone acetate.png has been listed at Commons:Deletion requests so that the community can discuss whether it should be kept or not. We would appreciate it if you could go to voice your opinion about this at its entry.
If you created this file, please note that the fact that it has been proposed for deletion does not necessarily mean that we do not value your kind contribution. It simply means that one person believes that there is some specific problem with it, such as a copyright issue. Please see Commons:But it's my own work! for a guide on how to address these issues. |
File:Cericlamine structure.png has been listed at Commons:Deletion requests so that the community can discuss whether it should be kept or not. We would appreciate it if you could go to voice your opinion about this at its entry.
If you created this file, please note that the fact that it has been proposed for deletion does not necessarily mean that we do not value your kind contribution. It simply means that one person believes that there is some specific problem with it, such as a copyright issue. Please see Commons:But it's my own work! for a guide on how to address these issues. |
File:Azaspirone-butyrophenone.png has been listed at Commons:Deletion requests so that the community can discuss whether it should be kept or not. We would appreciate it if you could go to voice your opinion about this at its entry.
If you created this file, please note that the fact that it has been proposed for deletion does not necessarily mean that we do not value your kind contribution. It simply means that one person believes that there is some specific problem with it, such as a copyright issue. Please see Commons:But it's my own work! for a guide on how to address these issues. |
File:Bolmantalate structure.svg has been listed at Commons:Deletion requests so that the community can discuss whether it should be kept or not. We would appreciate it if you could go to voice your opinion about this at its entry.
If you created this file, please note that the fact that it has been proposed for deletion does not necessarily mean that we do not value your kind contribution. It simply means that one person believes that there is some specific problem with it, such as a copyright issue. Please see Commons:But it's my own work! for a guide on how to address these issues. |